Browsing by Subject "Iodine compounds"
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Article
Attraction of iodide ions by the free water surface, revealed by simulations with a polarizable force field based on drude oscillators
(2005)Recent theoretical and experimental studies have shown that polarizable anions, such as iodide and bromide, preferentially accumulate close to the surface of electrolyte solutions. This finding is in sharp contrast to the ...
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Article
Dissecting the stabilization of iodide at the air-water interface into components: A free energy analysis
(2006)Recent experiments and simulations show that large chaotropic anions favor solvation at the water surface, mainly due to induction interactions dominated by ionic polarizabilities. We compare the solvation free-energy ...